1 Red Synthetic Diamond Crystal and a
Pyrope Garnet
The
two stones are held on the end of fibre optic light guides with Blutack
or similar.
The red synthetic diamond crystal was obtained
at Tucson 1998. The appearance was reminiscent of pyrope garnet.
The crystal was mainly a cubo-octahedron with further series
of stepped faces which related to other cubic crystal forms.
2 Magnetic Response
Filling
the motel room wash hand basin, the red crystal was floated on a
small piece of torn-off bubble pack. Using a small rare earth magnet (neodymium
boron ferrite), the resultant raft could just be towed very slowly
about the surface. It is actually safer to use a small wooden
raft, but in either case, check for a response of attraction before
adding the specimen.
The magnetic attraction indicated
a small level of response emanating from the inclusion content
of the synthetic diamond.
3 Bright Metallic Inclusions in Synthetic
Diamond
Large
(pique 1 or worse), inclusions of nickel/iron in synthetic diamond will
produce a dramatic response to a rare earth magnet. The inclusions
are typically bright metallic in appearance. They lack the
halo fractures or rosettes (black or silvery) which typify the inclusions
in many a natural diamond. The colourless faceted synthetic
diamond (0.18ct) shown, will jump approximately one centimeter
to attach to a rare earth magnet, but the large nickel iron inclusions
seen entrapped by the growing crystal explain this dramatic response. The
stone grade is clarity grade Pique 2.
4 Positive Magnetic Response
Here
a synthetic yellow diamond shows a positive attraction to a ferrous neodymium
boron Hanneman Magnetic Wand. The nickel /iron inclusions in
this synthetic diamond (courtesy DeBeers) are approximately diamond
clarity grade SI
The responses in Figs 47, 48 and
49 are positive for synthetic diamond.
The big question is. Do natural diamonds
exhibit any magnetic response of attraction?
Diamonds themselves produce no such magnetic
response, natural or synthetic. With help from Dr J Harris of Glasgow
University, we looked at natural diamonds with large inclusions of iron
sulphide eg Pyrrhotite and Pentlandite (chemically related to pyrites).
Using the raft technique in a large container of water, it was just
possible to demonstrate the slightest response to a rare earth magnet.
This observation does not contradict the above underlined statement
as follows:-
5 Pique 3 Inclusions in Natural
Diamond.
Typical black halo and rosette
inclusions in natural diamond are often iron sulphide minerals and
mineral films. Even large inclusions such as the one shown produce
only the slightest magnetic response, and would require suspension
in water or air to observe the merest attraction response. In a synthetic
diamond, such a sizeable inclusion would show a very dramatic
attraction response to a rare earth magnet as in Additionally, the
synthetic's inclusion would normally be silvery metallic in appearance.
Small inclusions in synthetic diamond (finer than pique 1) may be seen as dust clouds, or tiny pellets. These will still show a positive magnetic attraction on water if not in air, whereas such minimal inclusion content in natural diamond would produce neither of the magnetic responses described above. Most synthetic diamonds available to the trade at this time are from Russia, and available in various shades of yellow and colourless. Mostly a magnetic response of attraction can be observed. The Japanese Sumitomo synthetic diamonds are invariably yellow shades. Those seen by the writer exhibit no magnetic response in spite of having small ( clarity grade SI ) metallic looking inclusions. These Japanese synthetic diamonds may be identified by their fluorescence, grain lines aligned to cube faces, and strain birefringence patterns.
An excellent wall chart from GIA sets out a comprehensive overview of the distinction between natural and synthetic diamond. "A chart for the separation of natural and synthetic diamonds" Shigley J et al , Gems and Gemology Vol 31 No 4 . Winter 1995
Red Synthetic Diamond Absorption Spectrum
Using a small OPL diffraction spectroscope, and
a pen light torch to study the red diamond in Figs.1 and 2, it was immediately
possible to see a powerful band at approximately 637nm,a weaker 594nm and
three weaker bands in the same area.
Here was confirmation of irradiation and annealing
, and compares with the absorption pattern seen in treated pink natural
diamonds.
6 "Natural" Pink Diamonds
The
central pink diamond is a macle crystal of natural colour from the Argyle
Mine in Western Australia. The specimen exhibits no absorption lines
to a spectroscope at room temperature. The two faceted
round pink stones are colour enhanced by irradiation and heat treatment,
and exhibit very similar spectra to the synthetic red treated diamond as
follows:-
7 Three Diamond Spectra - Diffraction
spectrum left, prism spectrum right.
The
top two rows show the same suite of lines in the yellow/orange
zone observed in the two faceted stones in Fig 6.
The bands about 595nm and 637nm lines provide
visible evidence of annealing after initial irradiation. The line
at approximately 575nm is interesting, as it is reversible from absorption
(top row) to emission mode (second row) - in the manner of a ruby
693/694 doublet.
The bottom row spectra stem from the syntheic
red treated diamond, and produce a similar suite of lines to the
natural stones which have been colour enhanced.
The absorption pattern in the red synthetic stone was so evident, that it could be seen with a penlight torch and a 2" (50mm) OPL diffraction spectroscope in the Tucson Motel room. I think it permissable to mention here that Colin Winter's OPL spectroscope has been such a remarkable and inexpensive boon to gemmologists worldwide since 1976, that it is now blatantly copied. The measurements were achieved later with a Jena spectroscope from Eickhorst, and a measurement control system supplied by Nelson Gemmological Instruments.