Some Topaz Colour Enhancements
Cobalt-diffused
topaz along with treated colour and surface-coated topaz. The picture
shows three typical treated blue topaz, and one surface coated topaz ie
the specimen which has an iridescent appearance. The two types mentioned
are easily identified on a refractometer . The bluish green
stone in the centre is cobalt diffused, which can present a gemmological
problem for identification with a standard refractometer.
Four Cobalt-Diffused Topaz
All
the specimens observed produce a shadow column on the refractometer up
to the liquid limit of RI 1.81. The bluer stones do show a
shadow system at approx RI 1.61, 1.62, ( within the overall
scale shadow column) and the double refraction product approx.0.010.
The greener specimens (Courtesy SAN DIEGO LAB,
THOM UNDERWOOD GG ISA), give no inkling of their topaz identity on a refractometer.
When seen at Tucson, February 1998, Dr. W Hanneman was present, and his
"Jeweler's Eye" reflectivity meter registered all four stones in the refractive
area of cubic zirconia. This confirmed the refractometer's
indication of their high refraction above 1.81.
The non-refractometer reading in this case
stemmed from the cobalt-diffused surface, which is evidently altered (possibly
to a distinct mineral surface).
Without knowing the identity, I was challenged
by Hanneman and others to identify the stones. The only hint given
was that they were a good "Paraiba colour", in allusion to the distinct
shades of blue and green seen in the tourmalines from that Brazilian locality.
It should be said that the large size and jumbled juxtaposition threw doubt
on such an identity, especially when a fine one carat Paraiba specimen
can command $4000 per carat in the trade.
A penlight torch was produced, and I sat on the bed of the motel room and adopted a "Visual Optics" stance. My comments were as follows- "The refraction is low, there is double refraction, but not enough for tourmaline, and the B/D ratio is less than that of tourmaline". Without a scale I was forced to approximate that, "The RI is about 1.5 or 1.6, and the DR approx 0.10, which suggests an identity in the region of beryl or topaz.". The small audience was visibly impressed. The identity was then revealed as topaz.
The extraordinary fact for me was that here was a gemstone which indicated its RI above 1.81 on a refractometer, and the suggestion of CZ on a reflectivity meter. In spite of the instrumental suggestions, The Hodgkinson method literally saw through the subterfuge to recognise the innate optical properties which come from the body of the stone. The refractometer can, of course, only respond to the surface of a gemstone.
Stippled Appearance
A
view of the diffused topaz immersed in baby oil picks out the unnatural
stippled nature of the surface. For those familiar with the slippery
feel of topaz, this was decidedly lacking